Document Type : Research Paper

Authors

1 College of Dentistry, University of Anbar ,Ramadi, Iraq;

2 Department of Chemistry, College of Science, University of Anbar, Al-anbar, Iraq.

Abstract

The transition metal vanadium can easily move between the oxidation states +V, +IV, and +III and expand its sphere beyond tetrahedral coordination. It oxidizes into a brownish black trioxide, a blue-black tetroxide, or a reddish orange pentoxide when heated in air at various temperatures. The simple hydrothermal autoclave approach was used to synthesize vanadium pentoxide V2O5 nanoparticles from ammonium metavanadate NH4VO3. The synthesized sample was identification using X-Ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). The result confirms forming of V2O5 nanoparticles and the diameter was around 61- 167 nm. The transition metal vanadium can easily move between the oxidation states +V, +IV, and +III and expand its sphere beyond tetrahedral coordination. It oxidizes into a brownish black trioxide, a blue-black tetroxide, or a reddish orange pentoxide when heated in air at various temperatures. The simple hydrothermal autoclave approach was used to synthesize vanadium pentoxide V2O5 nanoparticles from ammonium metavanadate NH4VO3. The synthesized sample was identification using X-Ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). The result confirms forming of V2O5 nanoparticles and the diameter was around 61- 167 nm.

Keywords

Main Subjects

[1]. Ortiz, R. P., Facchetti, A., & Marks, T. J. (2010). Transparent Metal Oxide Nanowire Electronics. In Transparent Electronics: From Synthesis to Applications, John Wiley & Sons Ltd Chichester, (pp. 243-258).
[2]. Devan, R. S., Patil, R. A., Lin, J. H., & Ma, Y. R. (2012). One‐dimensional metal‐oxide nanostructures: recent developments in synthesis, characterization, and applications. Advanced Functional Materials, 22(16), 3326-3370.
[3]. Aachmann, F. L., Abe, I., Abergel, R. J., Abt, D., Achard, M. E., Acheson, J. F., ... & Atkinson, S. J. (2015). Encyclopedia of Inorganic and Bioinorganic Chemistry. DOI: 10.1002/9781119951438.
[4]. Guo, T., Yao, M. S., Lin, Y. H., & Nan, C. W. (2015). A comprehensive review on synthesis methods for transition-metal oxide nanostructures. CrystEngComm, 17(19), 3551-3585.
[5]. Baroch, E. F., & Updated by Staff. (2000). Vanadium and vanadium alloys. Kirk‐Othmer Encyclopedia of Chemical Technology, 1-18.
[6]. Rehder, D. (2013). Vanadium. Its role for humans. Interrelations between essential metal ions and human diseases, 139-169. 
[7]. Patel, N. (2021). Syntheses, Molecular Structures, Spectroscopic Characterization and Bio-Mimetic Activity of Vanadium Complexes. Doctoral dissertation, Maharaja Sayajirao University of Baroda (India)). ‏
[8]. Zibrov, I. P., Filonenko, V. P., Lyapin, S. G., & Sidorov, V. A. (2013). The high pressure phases β-and δ-V2O5: structure refinement, electrical and optical properties, thermal stability. High Pressure Research, 33(2), 399-408.
[9]. Taylor, P., Kusper, M., Hesabizadeh, T., Geoffrion, L. D., Watanabe, F., Herth, E., & Guisbiers, G. (2021). Synthesis of naked vanadium pentoxide nanoparticles. Nanoscale Advances, 3(7), 1954-1961.
[10].     Trachioti, M. G., & Prodromidis, M. I. (2020). Humidity impedimetric sensor based on vanadium pentoxide xerogel modified screen− printed graphite electrochemical cell. Talanta, 216, 121003.
[11].     Kumar, M. (2014). Hydrothermally Prepared Vanadium Oxide-Chetosan Nanocomposite for Electrocatalytic Application. Doctoral dissertation.
[12].     Ngo, T. D. (Ed.). (2020). Composite and Nanocomposite Materials: From Knowledge to Industrial Applications. BoD–Books on Demand.   
[13].     Singh, J., Singh, K. R., Kumar, M., Verma, R., Verma, R., Malik, P., ... & Kumar, D. (2021). Melt-quenched vanadium pentoxide-stabilized chitosan nanohybrids for efficient hydrazine detection. Materials Advances, 2(20), 6665-6675.
[14].     Li, Y., Zhou, M., Xia, Z., Gong, Q., Liu, X., Yang, Y., & Gao, Q. (2020). Facile preparation of polyaniline covalently grafted to isocyanate functionalized reduced graphene oxide nanocomposite for high performance flexible supercapacitors. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 602, 125172.  
[15].     Nourizadeh, H., Noori, M., Mirazimi, M., Badkoobehhezaveh, A. M., & Rashchi, F. (2021). Characterization and Ethanol-Sensing Behavior of Nanostructured Vanadium Pentoxide Recovered from Oil Fly Ash. International Journal of Environmental Research, 15, 985-999.