Document Type : Research Paper

Author

University of Anbar - Women Education College

10.37652/juaps.2009.15619

Abstract

: Acetylenic amine (N,N-Bis propargy piperazine) were synthesized and diagnosed in spectroscopic method (Uv-visibl and IR) and (C.H.N) analysis . Preparing and studying new complexes by using ligand that from acetylenic amine which using this purpose at the first time with metal chlorides(Mo+3 ,Cr+5 ,W+6 ,Fe+3 ). Studying of complexes by using suitable methods have been diagnosed in Uv-Visible, IR, Magnetic susceptibility , atomic absorption ,electric conductivity measurement and molar ratio, all result obtained from different techniques above which were found that their corresponding with the proposed structures for the prepared complexes . Complexes appeared liquid crystal properties therefore they have been studied careful (∆H, ∆S) of liquid crystal stages for both changes calculated which were found that their corresponding with the data in literature.

Keywords

Main Subjects

1- J.F. Ruffled," Acetylenic compounds", einhold book coporation, new york; 314, (1968).
2- D. Lednicer, "Organu\ic chemistry of drug synthesis", vol,1, (1966).
3- D.R.Learence,"Clinical pharmacology", p232-234, 2nd ed. (1963).
4- Gelman, Bukhovets, and Meilakh, Compt.rent. Acad. Sci. U.R.S.S., 46,105,(1945).
5- E.O.Chiai,"Aromatic Amine Oxide", Amsterdam, p15-17,(1967).
6- J.Chatt,L.A.Ducanson and R.G. Guy; Nature, 184 (1959).
7- Ibid.,827 (1961).
8- A.K.Kinashi,S.Takenaka and Kuseba Yash,. Mol., Crys., 67,49(1981).
9- A.H.Samir,M.Sc. Thesis, Baghdad University, Ibn-Alhaitham Education Collage (1997). 
10-  M.V.Rajasekn aran and P.T.Manoharan, Mol. Crys. Liq. Cry., 59, pp.197-206(1980).
11-  M. Ghedini, M. Longeri, ibid.,84, pp.207-211 (1982).
12-  V.B.Mochaline and T.S. Minervina, Zr. Og. Khim., 1 (10), 1725 (1965).
13-  K. Nakamato,'Infrared and Raman Spectra of inorganic and coordination compond', 4th Ed, Wiley intescince,New York, (1968).
14-  M. Sirokiand , M. Koren-Markovic,"Solvent Extraction and ion Exchangs", 6,771,(1988).
15-  B.N.Figgis,"Introduction to Ligand Fields", Interscince, New Yok (1966).