Interaction between Kaolin and DMSO: FTIR, XRD , thermodynamic and Nano studies

M. Hussein, Sabri; H. Shihab, Omar; S. Ibrahim, Sattar

doi:10.37652/juaps.2014.121534

Document Type : Research Paper

Authors

¹ University of Anbar – College of Science.

² University of Anbar – College of Women Education.

³ University of Anbar – College of Science

10.37652/juaps.2014.121534

Abstract

Intercalation of highly polar organic compound dimethylsulfoxide (DMSO) with kaolinite and the formation of interlamellar complexes has been studied, and characterized by X-ray diffraction (XRD), Fourier transform-infrared spectroscopy (FTIR). Interaction was found to be dependent on the particle size of kaolin raw material. Nature of interaction achieved through the formation of hydrogen bonds between DMSO and both AlOH and Si – O surface of kaolinite. Effect of temperature on equilibrium adsorption of methylene blue (MB) from aqueous solution using kaolin and kaolin – DMSO complexes also studied, the results were analyzed by Langmuir and Freundlich isotherms. Thermodynamic parameters such as ΔG, ΔH and ΔS were calculated. Results suggested that the MB adsorption on kaolin was spontaneous and exothermic process.

Keywords

Main Subjects

Chemistry

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Journal of University of Anbar for Pure Science

Interaction between Kaolin and DMSO: FTIR, XRD , thermodynamic and Nano studies

References

References

Volume 8, Issue 1
April 2014
Page 32-40

Interaction between Kaolin and DMSO: FTIR, XRD , thermodynamic and Nano studies

References

References

Volume 8, Issue 1April 2014Page 32-40

Volume 8, Issue 1
April 2014
Page 32-40